Guest guest Posted February 25, 2003 Report Share Posted February 25, 2003 Re: a newbie with so many questions about lotions, preservatives etc. > I love reading your posts Maurice. > > CS > > > > There are many natural ingredients that have antimicrobial activity. I > suggest that you search the message archives for " natural preservative " > (without the quotation marks > > ( " " ). Being a newbie, you should spend some time familiarizing yourself > the some basic concepts is preservation. > > > > You can visit the CosmeticInfo files area and go into the > preservative_Info folder: > > http://groups.yahoo.com/group/Cosmeticinfo/files/Preservative_Info/ > > > > Pay particular attention to this file: > > > http://groups.yahoo.com/group/Cosmeticinfo/files/Preservative_Info/Principle > s%20of%20Preservation.pdf > > > > > I need to know the name of the preservatives how to use it > > > > Here are links to popular (not natural) preservative systems: > > > > Phenonip > > http://www.nipa.com/products/pheno.htm > > > > Germall II, Germall 115, Germaben II, Germaben II-E, LiquaPar Oil, > Suttocide A, and LiquaPar PE > > http://www.ispcorp.com/products/hairskin/preserve/pres1.html > > > > Germall Plus > > http://www.ispcorp.com/products/hairskin/haircare/per12.html > > > > > and where I can buy it in Canada would be great. > > > > The first place that comes to mind is > > > > Sherri-Lee Gagnon > > Oshun Spirit Arts Ltd. > > 33511 Best Avenue > > Mission, BC V2V 5Z3 > > Voicemail: > > Fax: > > Email: info@... > > http://oshun.ca/ > > > > > I need to know everything about how to make lotions. > > > > I've been formulating lotions for a long time and I know I have a lot more > to learn before everything I need/want to know. What you need or want to > know about making lotions > > is defined by your own wants and needs. > > > > > What do I need to make lotions do I add glycerin to water or to oils? > > > > There is an old proverb, I believe it's a Chinese proverb, that says " the > longest journey begins with a single step " . And so, with that thought in > mind, let us begin our > > journey... > > > > Let's start with some basic understandings about creams and lotions. > Basically, when you formulate/create a lotion or cream, you are combining > two things, oil and water, > > that don't like one another. > > > > Water is a polar material. Things that " like " water are also polar > materials. Polar bears like water, but that not quite what I had in mind. > Polar materials are also called > > hydrophilic. The prefix " hydro- " means water and the suffix, " -philic " > means loving. So a hydrophilic material is water-loving. > > > > A non-polar material, like Canola Oil, is hydrophobic. The suffix -phobic > means hating. So hydrophobic materials hate water. Sometimes oils are called > lipophilic. In this > > case the prefix, " lipo- " means fatty. So a lipophilic material loves fatty > materials. > > > > So when we are making an emulsion, a cream or lotion, we are attempting to > combine water with oil or a hydrophilic material with a hydrophobic material > or a hydrophilic > > material with a lipophilic material. Different ways of saying the same > thing. > > > > If we were to pour some Olive Oil into a bowl of water, the Olive Oil > would float to the top rather quickly. If we stirred the Olive Oil & Water > mixture with a whisk, the Canola > > Oil would breakup into small droplets or globules but on standing, the > smaller globules would come together and becomes one larger globule. The > smaller globules are > > coalescing to form larger globules. This process will continue until we > are left with two layers. > > > > In order to bring these two incompatible materials, like Olive Oil and > water, together, we need is something that will make the water like the oil > and will also make the oil like > > the water. > > > > Going right to the point, what we need is an emulsifier or two or three. > The most common emulsifiers used by cosmetic chemists are a group of raw > materials called > > nonionic emulsifiers. > > > > The word " nonionic " mean no charge. The nonionic emulsifier has no > positive or negative charge. But nonionic emulsifiers have a unique property > that is of special value to > > the formation of emulsions. > > > > All emulsifier have two parts. In many ways, similar to a bar magnet. A > bar magnet has a north pole and a south pole. Nonionic emulsifiers also have > two poles or parts. > > > > An emulsifier molecule has one part that loves water and one part loves > oil. The water loving part is called hydrophilic; " hydro-` meaning water and > " -philic " meaning to love or > > like. > > > > The other part of the emulsifier molecule is lipophilic; If " lipo- " means > fat or oil, then lipophilic means oil loving. > > > > Therefore, an emulsifier has a hydrophilic part and a lipophilic part. > The balance of these two portions of the emulsifier gives us the > Hydrophile-Lipophile Balance (HLB). The > > HLB of emulsifiers can be calculated or determined through trial and > error. > > > > One tool that is used by many formulators of creams and lotions is the HLB > system. The HLB System is a tool; not a rule. It's not an easy short cut to > the perfect > > emulsion. The HLB System dramatically simplifies the choice of surfactants > necessary to meet emulsion formulation requirements. It is based on the > balance between the > > hydrophilic and the lipophilic proportions that give each surfactant its > functionality. > > > > It is a tool that will guide you in the right direction. > > > > The Hydrophile-Lipophile Balance System or HLB System was developed by the > HLB System is a tool, not a rule. It's not an easy short cut to the perfect > emulsion. The > > HLB System dramatically simplifies the choice of surfactants necessary to > meet emulsion formulation requirements. It is based on the balance between > the hydrophilic and > > the lipophilic proportions that give each surfactant its functionality. > > > > It is a tool that will guide you in the right direction. > > > > The HLB System was developed by C. (Bill) 1949 while he > was a chemist at the Atlas Powder Company, which eventually became ICI > Surfactants and is now > > called Uniqema. > > > > According to the HLB system, each nonionic emulsifier has a HLB and each > oil/wax has a Required HLB. > > > > Here are the HLB's of some nonionic emulsifiers: > > > > Glycol Distearate (HLB = 1) > > Sorbitan Trioleate (HLB = 1.8) > > Glycol Stearate (HLB = 2.9) > > Sorbitan Sesquioleate (HLB = 3.7) > > Glyceryl Stearate (HLB = 3.8) > > Sorbitan Oleate (HLB = 4.3) > > Sorbitan Isostearate (HLB = 4.7) > > Sorbitan Stearate (HLB = 4.7) > > Oleth-2 (HLB = 4.9) > > Steareth-2 (HLB = 4.9) > > Ceteth-2 (HLB = 5.3) > > Glyceryl Stearate SE (HLB = 5.8) > > PEG-4 Dilaurate (HLB = 6) > > Methyl Glucose Sesquistearate (HLB = 6.6) > > Sorbitan te (HLB = 8.6) > > PEG-40 Sorbitan Peroleate (HLB = 9) > > Laureth-4 (HLB = 9.7) > > PEG-20 Almond Glycerides (HLB = 10) > > PEG-25 Hydrogenated Castor Oil (HLB = 10.8) > > Glyceryl Stearate (and) PEG-100 Stearate (HLB = 11) > > Polysorbate 85 (HLB = 11) > > Oleth-10 (HLB = 12.4) > > Ceteth-10 (HLB = 12.9) > > PEG-8 te (HLB = 13) > > Polysorbate 60 (HLB = 14.9) > > Isosteareth-20 (HLB = 15) > > PEG-20 Methyl Glucose Sesquistearate (HLB = 15) > > PEG-60 Almond Glycerides (HLB = 15) > > Polysorbate 80 (HLB = 15) > > Ceteareth-20 (HLB = 15.2) > > Oleth-20 (HLB = 15.3) > > Steareth-21 (HLB = 15.5) > > Ceteth-20 (HLB = 15.7) > > Isoceteth-20 (HLB = 15.7) > > Polysorbate 20 (HLB = 16.7) > > Laureth-23 (HLB = 16.9) > > PEG-100 Stearate (HLB = 18.8) > > PEG-80 Sorbitan te (HLB = 19.1) > > > > And here are the Required HLBs of several oil/waxes: > > > > Caprylic/Capric Triglyceride (RHLB = 5) > > Caprylic/Capric Triglycerides (and) Matricaria Extract (RHLB = 5) > > Dimethicone (RHLB = 5) > > Almond Oil (RHLB = 6) > > Carrot (Daucus Carota Sativa) Seed Oil (RHLB = 6) > > Daucus Carota Sativa (Carrot) Root Extract (RHLB = 6) > > Peanut Oil (RHLB = 6) > > Retinyl Palmitate (RHLB = 6) > > Sunflower (Helianthus Annuus) Seed Oil (RHLB = 6) > > Theobroma Cacao (Cocoa) Seed Butter (RHLB = 6) > > Tocopherol (RHLB = 6) > > Jojoba (Buxus Chinensis) Oil (RHLB = 6.5) > > Apricot Kernal Oil (RHLB = 7) > > Avocado (Persea Gratissima)Oil (RHLB = 7) > > Borage (Borago Officinalis) Seed Oil (and) Tocopherol (and) Ascorbyl > Palmitate (RHLB = 7) > > Canola Oil (RHLB = 7) > > Dog Rose ( Canina) Hips Oil (RHLB = 7) > > Evening Primrose Oil (RHLB = 7) > > Grape (Vitis Vinifera) Seed Oil (RHLB = 7) > > Macadamia (Ternifolia) Nut Oil (RHLB = 7) > > Olive (Olea Europaea) Oil (RHLB = 7) > > Oryza Sativa (Rice Bran) Oil (RHLB = 7) > > Petrolatum (RHLB = 7) > > PPG-15 Stearyl Ether (RHLB = 7) > > Sesame (Sesamum Indicum) Oil (RHLB = 7) > > Soybean (Glycine Soja) Oil (RHLB = 7) > > Sweet Almond (Prunus Amygdalus Dulcis) Oil (RHLB = 7) > > Babassu Oil (RHLB = 8) > > Brazil Nut Oil (RHLB = 8) > > Ceresin (RHLB = 8) > > Coconut Oil (RHLB = 8) > > Emu Oil (RHLB = 8) > > Mangifera Indica (Mango) Seed Butter (RHLB = 8) > > Safflower (Carthamus Tinctorius) Oil (RHLB = 8) > > Shea Butter (Butyrospermum Parkii) (RHLB = 8) > > Myristyl Myristate (RHLB = 8.5) > > Diisopropyl Adipate (RHLB = 9) > > Hybrid Safflower (Carthamus Tinctorius) Oil (RHLB = 9) > > Anhydrous Lanolin (RHLB = 10) > > Cetyl Esters (RHLB = 10) > > Cetyl Palmitate (RHLB = 10) > > Lanolin (RHLB = 10) > > Mineral Oil (RHLB = 10.5) > > Isopropyl Myristate (RHLB = 11.5) > > Isopropyl Palmitate (RHLB = 11.5) > > Beeswax (RHLB = 12) > > C12-15 Alkyl Benzoate (RHLB = 13) > > Castor (Ricinus Communis) Oil (RHLB = 14) > > Stearic Acid (RHLB = 15) > > Cetearyl Alcohol (RHLB = 15.5) > > Cetyl Alcohol (RHLB = 15.5) > > Stearyl Alcohol (RHLB = 15.5) > > > > The national Formulary (NF) defines Emulsifying Wax NF as " a waxy solid > prepared from Cetostearyl Alcohol containing a polyoxyethylene derivative of > a fatty acid ester of > > sorbitan. Cetostearyl Alcohol is a blend of Cetyl Alcohol and Stearyl > Alcohol. > > > > Examples of a " polyoxyethylene derivative of a fatty acid ester of > sorbitan " include: > > > > Polysorbate 20 (HLB = 16.7) > > Polysorbate 60 (HLB = 14.9) > > Polysorbate 80 (HLB = 15) > > Polysorbate 85 (HLB = 11) > > > > The Required HLB of Cetyl Alcohol and Stearyl Alcohol is 15.5. So we must > choose a " polyoxyethylene derivative of a fatty acid ester of sorbitan " that > has a HLB close to > > 15.5. Polysorbate 80 should work, but, since Polysorbate 80 is a liquid, > the resultant mixture would probably soft and/or mushy. > > > > Polysorbate 60 is firmer and has a HLB of 14.9. I believe Emulsifying Wax > NF is a blend of Cetyl Alcohol and Stearyl Alcohol and Polysorbate 60. > > > > So, Emulsifying Wax NF is a self-emulsifying fatty alcohol. In theory and > practice, you can eliminate Emulsifying Wax NF but adding the Cetyl Alcohol > and Stearyl Alcohol > > and Polysorbate 60 as separate ingredients. > > > > > I tried to make a cleaning milk but didn't succeed maybe someone is > > > willing to share her recipes. > > > > What do you want to emulsify? What chemicals do you have? > > > > > I went to the bathstuff pages and was surprise I couldn't find any > > > links to web sites about all the questions I asked maybe someone has > > > many links and is willing to share. Don't you think that it would be > > > a good idea to share our links of best web page? just an idea, I am > > > sure it could help many newbies. > > > > http://www.paddocklabs.com/publications/secundum/secart41.html > > http://www.zenitech.com/documents/hlb_english.pdf > > http://www.zenitech.com/primary_ingredients_zenitech.pdf > > > > And you should/must spend sometime browsing the CosmeticInfo files area: > > http://groups.yahoo.com/group/Cosmeticinfo/files/ > > > > We have a very large library of files. In fact, we have almost exceeded > our storage space and have opened a second files library at: > > http://groups.yahoo.com/group/cosmeticinfo2/files/ > > > > You'll have to join Cosmeticinfo2 before you can access the files. > > > > You should also visit the CosmeticInfo links page: > > http://groups.yahoo.com/group/Cosmeticinfo/links > > > > And last, but not least are the message archives. The message archives > cover an incrediable amount of information. > > > > > About all these questions you can e-mail me privately if you wish. > > > > Actually, I would like to discourage this. There are many lurkers that > will learn from the open correspondence. > > > > Maurice > > > > -------------------------------------------------------- > > Maurice O. Hevey > > Convergent Cosmetics, Inc. > > http://www.ConvergentCosmetics.com > > ------------------------------------------------------- > > > > > > > > > > > > > > Post message: Cosmeticinfo > > Subscribe: http://groups.yahoo.com/group/Cosmeticinfo > > Unsubscribe: Cosmeticinfo-unsubscribe > > List owner: Cosmeticinfo-owner > > URL to this page: http://groups.yahoo.com/group/Cosmeticinfo > > > > > > > > > > Quote Link to comment Share on other sites More sharing options...
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